Descriptors of InZrOx vs ZnZrOx Catalysts for CO2 Hydrogenation to Methanol

Speciation study and benchmarking of standardized indium-zirconium (InZrO _x ) and zinc-zirconium oxide (ZnZrO _x ) materials prepared by flame spray pyrolysis enables common reactivity descriptors for CO₂ hydrogenation to methanol to be classified. For both families, isolated In/Zn atoms are the optimal speciation for performance. The higher activity of isolated InZrO _x is linked to its superior surface oxygen vacancy chemistry and hydrogen addition ability.

Abstract

Indium-zirconium (InZrO _x ) and zinc-zirconium oxides (ZnZrO _x ) have emerged as highly selective and stable catalysts for CO₂ hydrogenation to methanol, a versatile energy carrier. However, the disparity in synthesis methods, catalyst formulations, and structures previously studied precludes quantitative comparisons between the two families. Herein, a rigorous framework is pioneered to benchmark InZrO _x and ZnZrO _x materials prepared by a standardized flame spray pyrolysis synthesis platform, enabling consistently high surface areas and tunable metal speciation ranging from isolated atoms (<5 mol%) to predominantly nanoparticles (>10 mol%). Isolated indium and zinc species are commonly identified to be optimal for activity and methanol selectivity in their respective families, maximizing CO₂ and H₂ activation abilities. InZrO _x outperforms ZnZrO _x across speciations and is less structure sensitive, as deviations from atomic dispersion is less detrimental on performance for the former. Focusing on representative catalysts featuring saturation of isolated species, the higher activity of 5 mol% InZrO _x over its ZnZrO _x counterpart is linked to differences in surface oxygen vacancy chemistry, a lower degree of product inhibition, and more facile hydrogenation of the formate intermediate to methoxy. The identification of reactivity descriptors governing both families facilitates the development of unified guidelines in designing reducible oxide catalysts.