Unconventional catalytic kinetics of dual field regulated pyrochlore-type high-entropy ceramics towards the Li2S4 intermediate
Energy Environ. Sci., 2025, Advance ArticleDOI: 10.1039/D5EE01215E, Paper Open Access   This article is licensed under a Creative Commons Attribution 3.0 Unported Licence.Lin Zhou, Handing Liu, Ji-Xuan Liu, Xinrui Zhang, Yixi Yao, Ruirui Wang, Ziliang Chen, Prashanth W. Menezes, Guo-Jun ZhangReducing the electronegativity and crystal field splitting energy can adjust the Zr–O covalency and electronic structure. This, in turn, weakens the adsorption ability of pyrochlore high-entropy oxides towards Li2S4 and enhances sulfur redox catalysis.To cite this article before page numbers are assigned, use the DOI form of citation above.The content of this RSS Feed (c) The Royal Society of Chemistry
DOI: 10.1039/D5EE01215E, Paper


Reducing the electronegativity and crystal field splitting energy can adjust the Zr–O covalency and electronic structure. This, in turn, weakens the adsorption ability of pyrochlore high-entropy oxides towards Li2S4 and enhances sulfur redox catalysis.
To cite this article before page numbers are assigned, use the DOI form of citation above.
The content of this RSS Feed (c) The Royal Society of Chemistry